Nanoimprint of dehydrated PEDOT:PSS for organic photovoltaics.
نویسندگان
چکیده
We demonstrate the fabrication of poly(3,4-ethylenedioxythiophene) poly(styrenesulfonate) (PEDOT:PSS) nanogratings by a dehydration-assisted nanoimprint lithographic technique. Dehydration of PEDOT:PSS increases its cohesion to protect the nanostructures formed by nanoimprinting during demolding, resulting in the formation of high quality nanogratings of 60 nm in height, 70 nm in width and 70 nm in spacing (aspect ratio of 0.86). PEDOT:PSS nanogratings are used as hole transport and an electron blocking layer in blended poly(3-hexylthiophene-2,5-diyl) (P3HT):[6,6]-penyl-C61-butyric-acid-methyl-ester (PCBM) organic photovoltaic devices (OPV), showing enhancement of photocurrent and power efficiency in comparison to OPV devices with non-patterned PEDOT:PSS films.
منابع مشابه
Insights on the Optical Properties of Poly(3,4-Ethylenedioxythiophene):Poly(styrenesulfonate) Formulations by Optical Metrology
Poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) is among the most widely used polymers that are used as printed transparent electrodes for flexible Organic Electronic (OE) devices, such as Organic Photovoltaics (OPVs). The understanding of their optical properties and the correlation of the optical properties with their electronic properties and metallic-like behavior can le...
متن کاملGraphene as transparent conducting electrodes in organic photovoltaics: studies in graphene morphology, hole transporting layers, and counter electrodes.
In this work, organic photovoltaics (OPV) with graphene electrodes are constructed where the effect of graphene morphology, hole transporting layers (HTL), and counter electrodes are presented. Instead of the conventional poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) PEDOT:PSS HTL, an alternative transition metal oxide HTL (molybdenum oxide (MoO(3))) is investigated to address the iss...
متن کاملGraphene Oxide:Single-Walled Carbon Nanotube-Based Interfacial Layer for All-Solution-Processed Multijunction Solar Cells in Both Regular and Inverted Geometries
Over the past decade, advances in material synthesis and interfacial engineering have produced more efficient polymer solar cells with improved absorption of the solar irradiation and charge carrier transport that have led to continuously increased power conversion efficiencies (PCE), recently surpassing 8%.[1] In parallel to the material design and engineering in the active layer, novel organi...
متن کاملTuning hole charge collection efficiency in polymer photovoltaics by optimizing the work function of indium tin oxide electrodes with solution-processed LiF nanoparticles
By varying the density of solution-processed lithium fluoride (sol-LiF) nanoparticles at the interface between tin-doped indium oxide (ITO) and poly(3,4ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS), we have demonstrated that the electronic hole collection efficiency of an organic photovoltaic cell can be optimized through tuning the energy level alignment at the ITO/PEDOT:PSS inter...
متن کاملSolution-processable graphene oxide as an efficient hole transport layer in polymer solar cells.
The utilization of graphene oxide (GO) thin films as the hole transport and electron blocking layer in organic photovoltaics (OPVs) is demonstrated. The incorporation of GO deposited from neutral solutions between the photoactive poly(3-hexylthiophene) (P3HT):phenyl-C61-butyric acid methyl ester (PCBM) layer and the transparent and conducting indium tin oxide (ITO) leads to a decrease in recomb...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
- Nanotechnology
دوره 22 48 شماره
صفحات -
تاریخ انتشار 2011